Whether or not buckling modes with $n>1$ exists depends on how you look at the structure.
As @hazzey notes in his answer, columns with bracing may display buckling modes with $n>1$. These buckling modes, however, are simply equivalent to the $n=1$ modes of the individual segments that compose the column. To be clear, this doesn't mean that the segments behave independently (you'll never have two consecutive unbraced lengths buckling to the same side), only that any $n>1$ mode can be composed by a series of continuous $n=1$ modes for the unbraced lengths.
So, if you have a column with a single bracing which buckles, do you consider that an $n>1$ mode for the entire column or an $n=1$ mode for each of the unbraced lengths? Both? Your call.
To paraphrase @starrise's comment on @hazzey's answer, this can be demonstrated by looking at the buckling equation:
\begin{align}
P &= \left(\dfrac{n}{L}\right)^2\pi^2EI \\
P_{column,\,n=2} &= \left(\dfrac{2}{L}\right)^2\pi^2EI \\
P_{segment,\,n=1} &= \left(\dfrac{1}{\frac{L}{2}}\right)^2\pi^2EI = \left(\dfrac{2}{L}\right)^2\pi^2EI \\
\therefore P_{column,\,n=2} &= P_{segment,\,n=1}
\end{align}