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I read about absorption chillers and found out that the water is evaporated/boiled off at the generator.

Water boils over at about 3.7 Celsius in the near-vacuum conditions in the generator. Now the boiling point is also the condensing point! But when this same water condenses at 35 Celsius in the condenser despite the pressure being the same near-vacuum (or is it?), it sends my brain to physics hell.

The only explanation my pea-brain can think of is that the steam itself creates pressure that sort of increases... I hate to say it... its own boiling (thus condensing) point. And so now it condenses at 35 rather than 3 Celsius. Does this even make sense to you?

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  • $\begingroup$ you've missed how the system functions. The generator and condenser are at the same pressure, as are the evaporator and absorber. $\endgroup$
    – Tiger Guy
    Jun 4 at 7:19
  • $\begingroup$ Then why and how does the hot vapour become cool liquid upon entering the evaporator??!! $\endgroup$
    – El Flea
    Jun 4 at 7:26
  • $\begingroup$ the heat of fusion is available for cooling due to the liquid flashing to vapor in the lower pressure. $\endgroup$
    – Tiger Guy
    Jun 4 at 7:29
  • $\begingroup$ Bro. Water boils over at 3 Celsius at the generator, right or not? Vapour pressure is reduced at the condenser because it is cooled to 35 Celsius. The ONLY thing that can happen now is that the vapour partially, PARTIALLY, condenses. So you say that only that water evaporates back into steam (thus chills water) while the rest of the uncondensed vapour is just there to make the cycle inefficient??? $\endgroup$
    – El Flea
    Jun 4 at 7:53
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Here is a quick walk-through of a typical ammonia-water chiller you may find useful.

  1. An aqueous ammonia concentrated solution is evaporated using a heat source to generate a nearly dehydrated ammonia vapor. The vapor is at a decently high pressure.

  2. The dehydrated ammonia vapor continues to the condenser where it is cooled and condensed. The pressure is slightly lowered.

  3. The condensate then passes through an expansion valve lowering the temp and pressure of the fluid.

  4. The ammonia liquid now enters the evaporator where it takes on heat from the substance being cooled (where the refrigeration takes place). After taking on this heat the ammonia liquid flashes and exits the evaporator as a vapor.

  5. After exiting the evaporator as a vapor ammonia is pulled into the liquid phase by absorption. In the absorber unit an ammonia water mist is usually introduced. The ammonia vapor has a high affinity to this solution. The concentrated ammonia liquid is collected usually at the bottom of the unit and pumped to the generator. Where step 1 begins.

You will notice unlike the traditional refrigeration cycle we are using a pump to take the fluid from low to high pressure. There isn’t a compressor.

Now to answer your specific concern about how water is boiling and condensing at different temperatures:

  • In the absorption chiller, the condenser is at a relatively high
    pressure. This is because its feed is coming from the generator whose purpose is to heat up the aqueous ammonia solution to achieve
    separation from the two compounds. The effluent hot dehydrated
    ammonia's saturated pressure will therefore be relatively high.

  • In the evaporator section of the chiller (downstream and where we are chilling the external fluid) the entering ammonia liquid concentrate is at a lower temp (Te) and pressure. Why? Because it was just
    throttled through an expansion valve. Hence the saturated vapor temp of evap unit is lower than that of condenser unit.

To Answer your specific concern about the applicability of ammonia water chilling to LiBr.

  • How does ammonia-water chiller apply to a different technology like water-LiBr chiller? Simply put the coolant role played by ammonia in the example is played by water in the LiBr chiller. The absorption role played by water in the example above is played by LiBr.

In the absorption chilling cycle pressures and temperatures will vary greatly depending on what unit you are talking about, but there isn’t any whacky thermo going on here. You described the generator being coldest and at low pressure in the problem statement, usually the generator is at the highest pressure and the hottest. I don’t know your set-up but you may have confused the generator with the evaporator unit!

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    $\begingroup$ I never said the generator is the coldest. Also, if you could edit your answer so it relates the LiBr cycle, I would appreciate as I am using WATER as the refrigerant and salt as the absorbant. Also, people like you are forever in my heart, for their sincerity, as its rare around here. $\endgroup$
    – El Flea
    Jun 11 at 8:58
  • $\begingroup$ @ElFlea see edit $\endgroup$
    – Feynman137
    Jun 12 at 2:00

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