The definition of the thermal boundary layer is that of the distance across a boundary layer from the wall to a point where the flow temperature has essentially reached the 'free stream' temperature, $T_{0}$. This distance is defined normal to the wall in the y-direction
The Prandtl number is defined as the ratio of momentum diffusivity to thermal diffusivity. The equation which mostly reflects that (there are other forms) is probably:
$$Pr = \frac{c_p \mu}{k}$$
So the smaller the Prandtl number the higher thermal diffusivity there is in the material compared to the momentum diffusivity. However greater diffusivity means that the heat from the wall penetrates easier in the fluid flow and therefore the temperature of the wall affects a larger area in the liquid. So, the greater the heat conductivity the further, inside the material the $T_w$ will have an affect.
Essentially the TBL, shows at which distance the flow is thermally independant of the boundary walls. In that respect you might be able to understand that, increasing heat conductivity (and smaller Prandtl numbers) results in thicker boundary layer.
Relation to velocity boundary layer
You have to keep in mind that when you change the Prandtl number by changing the $k$ heat conductivity, you don't alter the kinematic behaviour. I.e. the velocity boundary layer remains the same, and its determined by the following equation:
$$\delta _{v} = 5.0 \sqrt\frac{v\cdot x}{u_0} $$
where:
- $\delta _{v} $ is the thickness of the velocity boundary layer thickness
- $u_{0}$ is the freestream velocity
- $x$ is the distance downstream from the start of the boundary layer
- $\nu$ is the kinematic viscosity
The velocity boundary layer thickness is mainly dependent on the viscosity, in a similar manner to the thermal boundary layer. In a similar manner because there is an analogy that:
- greater viscosity means that higher forces can be transfer through the material, while
- greater heat conductivity means that more heat can be transferred through the material.
So the higher the viscosity, the greater the effect of the boundary conditions (velocity equals to zero) on the flow.
The thickness of the thermal boundary layer is given by:
$$\delta_T = 5.0 \sqrt\frac{v\cdot x}{u_0} Pr^{-1/3}$$
where:
- $\mathrm {Pr}$ is the Prandtl Number
- $u_{0}$ is the freestream velocity
- $x$ is the distance downstream from the start of the boundary layer
- $\nu$ is the kinematic viscosity
Therefore, the thermal and velocity boundary are related by :
$$\delta_T = \delta _{v} Pr^{-1/3}$$
You can write the above equation in the following form:
$$Pr= \left(\frac{\delta_v }{\delta_T} \right)^3$$