I believe that you have two possible approaches to an energy balance.

System A
The walls allow heat flow. The defining equations are
$$
P_i = q_x + q_a + P_o \\
q_x = \epsilon_{HS} (1 - \epsilon_L) P_i \\
q_a = (T_c - T_a) / R_T \\
R_T = R_c + R_w + R_a \\
R_c = 1/h_c A_w\ \ R_w = w_w / A_w k_c\ \ R_a = 1/h_a A_w
$$
The balance here is with power input, heat flow out of the fins, heat flow across the container, and cooling power output. The heat flow from the fins is the heat sink efficiency times the heat produced by the lamps as determined from the lamp efficiency (for light production). The heat flow across the wall is a thermal resistance calculation. In this case, you assume / calculate the overall thermal resistance $R_T$. You define the fin efficiency $\epsilon_{HS}$ and lamp efficiency $\epsilon_L$. You set the air temperature $T_a$ and power input $P_i$. What is left is the cooling power that you need $P_o$. The maximum is when $\epsilon_{HS} = 0$ (all lamp heat is dumped to the container) and $\epsilon_L = 0$ (the lamp produces only heat and no light). This approach allows you to size the cooling unit for the maximum required cooling rate $P_{o,max}$ (W) at the output.
System B
The system is adiabatic. The defining equations are
$$
q_L = q_c \\
q_L = (1 - \epsilon_{HS}) (1 - \epsilon_L) P_i \\
q_c = (T_c - T_x) / R_c \\
R_c = 1/h_c A_c
$$
The balance here is heat flow from the lamps and heat flow to the cooling unit. Assume that all heat produced by the lamps is dumped perfectly to the system. The heat flow to the cooling unit is defined by the thermal resistance. This approach allows you to design the temperature, efficiency (convection coefficient), and area of the cooling unit. This will again give a maximum design when $\epsilon_{HS} = 0$ and $\epsilon_L = 0$.
Questions?
Here are the questions that I find are left to address:
- Which system model is more appropriate, conducting walls or insulated walls (System A or System B)?
- How much heat will the lamps dump to the container (what are $\epsilon_{HS}$ and $\epsilon_L$)?
- How effective is the cooling unit (what are its nominal values of $h_c$ and $A_c$)?
Notes
- System A assumes the chamber is hotter than the surrounding air. System B does not care.
- Neglect radiation, especially in System A. Unless something in the system is above a few hundred oF, radiation is of third order consequence.
- This assumes that all heat produced by the lamps is dumped perfectly to the system. When the lamps are hot above the system, convection is nearly non-existent. The chamber will have a hot zone at the top and a cool zone at the bottom. You must adjust the placement of hot and cold elements accordingly.
- This analysis only gives a picture of how to find the maximum design parameters. The next step may be to decide how much control you want / need on the cooling unit.
Edit (After the Fact)
The original question was ...
I really would like to know what fraction of heat will be diverted into the growth chamber vs what fraction of heat will exit through the heat sink,
The variable you want to determine is $\epsilon_{HS}$. Based on the system picture, I can suggest a simple experiment. Set up the chamber with everything as desired but exclude the cooling system. Put a thermocouple in the chamber. Run the lamps until the internal temperature stabilizes. Use the equations to back-calculate a value or estimate for $\epsilon_{HS}$.