Note, as I have my degree in chemistry, I denote "=>" as the next step in the equation. Also, sorry for any obvious mistakes that I made - as I mentioned, my degree is not in engineering. Thanks!
I am considering a design for a PET spherical toy ball. The ball will have a radius of 0.07 m that will have pressurized air in it at a pressure of 5.81 atm (588698.3 Pa). Also, the ball will include a 35 nm coating of Reduced Graphene Oxide (RGO) as a durable coating on the outside of the ball.
To get the thickness of the walls of the ball, I know that the ultimate tensile strength of PET is 55 MPa. Because I want a 15% safety factor for the ball, I do the following calculation: $$(1-15\%)\cdot55 = 46.75\text{ MPa} = 46750000\text{ Pa}$$
I then use the reduced ultimate tensile strength to find the thickness of the wall using the formula for a thin-walled sphere where $p$ is pressure, $t$ is thickness, $r$ is radius, and $\sigma$ is stress:
$$\begin{gather} \sigma = \dfrac{pr}{2t} \\ 46750000 = \dfrac{588698.3 \cdot 0.07}{2t} \\ \therefore t = 4.41\times 10^{-4}\text{ m} \end{gather}$$
I can calculate the burst pressure of the sphere $P$ for pressure (gauge) inside sphere, $FS$ for factor of safety, $\sigma$ for allowable stress and additionally $R_i$ for inner radius, $R_o$ for outer radius:
$$P = \dfrac{(R_o^2-R_i^2)\sigma}{(R_i^2)FS}$$
For calculation of bursting pressure, we take $\sigma$ as ultimate stress for a given material and put $FS=1$.
Note here that I chose the express the ultimate tensile strength of PET as $5.5 \times 10^7$:
$$P = \dfrac{((0.07 + 4.41 \times 10^{-4})^2 - 0.07^2)\cdot 5.5 \times 10^7}{0.07^2 \times 1} = 695183.67\text{ Pa} = 6.86\text{ atm}$$
I now want to calculate the volume of PET needed to create a sphere of the desired dimensions:
$$\begin{align} V &= \dfrac{4}{3}\pi \left(\left(\dfrac{d_o}{2}\right)^3 - \left(\dfrac{d_i}{2}\right)^3\right) \\ &= \dfrac{4}{3}\pi \left(\left(\dfrac{0.140 + 4.41 \times 10^{-4}}{2}\right)^3 - \left(\dfrac{0.140}{2}\right)^3\right) \\ &= 1.36 \times 10^{-5}\text{ m}^3 \end{align}$$
I now want to calculate the volume of Reduced Graphene Oxide (RGO) to apply to the surface of the sphere:
$$\begin{align} V &= \dfrac{4}{3}\pi \left(\left(\dfrac{d_o}{2}\right)^3 - \left(\dfrac{d_i}{2}\right)^3\right) \\ &= \dfrac{4}{3}\pi \left(\left(\dfrac{0.140 + 4.41 \times 10^{-4} + 35 \times 10^{-9}}{2}\right)^3 - \left(\dfrac{0.140 + 4.41 \times 10^{-4}}{2}\right)^3\right) \\ &= 1.084366 \times 10^{-9}\text{ m}^3 \end{align}$$
Can you see any mistakes in my calculations?
Please do not ask why I am using PET as a material or other design decisions like that. There are good reasons for them.