You've got your terms confused.
The maximum shear stress at the midpoint is equal to
$$\tau_{max} = 1.5\frac{V}{A} = 1.5\overline\tau$$
where $\dfrac{V}{A}=\overline\tau$, which is the average shear stress along the entire section.
That is the only viable comparison to be made, stress to stress. And having a maximum stress greater than the average stress is totally reasonable.
Your doubt, however, is that "the shear force at this point is equal to $1.5V$". That is not the case. There is no shear force at any point in the section. There is only a shear stress. The entirety of the shear stress must then be integrated over the area to obtain the shear force.
You may be thinking "stress is just equal to force divided by area, so can't I just do
$$\begin{align}
\tau &= \frac{V}{A} \\
\therefore \tau_{max} &= \frac{V_{max}}{A} \\
\tau_{max} &= 1.5\frac{V}{A} \\
\frac{V_{max}}{A} &= 1.5\frac{V}{A} \\
V_{max} &= 1.5V
\end{align}$$
and prove that the shear force at the midpoint is greater than the applied shear force?" But I already beat you to it. After all, as I mentioned at the start, $\dfrac{V}{A}$ gives you the average stress along the section. So $\dfrac{V_{max}}{A}$ is equivalent to the following stress profile, which clearly isn't the one you're expecting:
